Take a scuff pad or fine sandpaper and go over the entire chrome part you’re about to paint. I wonder if you could make a nickel bath which is short of wetting agent to get some pitting.

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Most paints will not wet it, and will not adhere at all.

How to paint over chrome plated metal. Honestly, painting over chrome doesn't have to be very costly. Allow to dry between coats. If left unchecked, rust can eat through the upper chrome plating and nickel plating underneath to expose the base of raw steel.
This guide is applicable when painting most bare metal surfaces. If you were to strip the chrome, and then roughen the nickel with fine sandpaper [affil. Be sure to etch into the chrome surface with some coarse sandpaper or even a small grinder, in this instance i decided to use 80 grit sand paper on an orbital sander and did the hard to reach spots with 80 grit by hand.
All you have to do is go to any home improvement store (lowes is the most reliable) and talk to one of the paint specialists. Also includes different paint types. Always ensure that you allow at least 24 hours for the black base coat to dry before you continue to apply your chrome spray paint.
Stripping the chrome with hydrochloric acid is fast and effective, but dangerous, and leaves you with acid to dispose of. You could sand the item down with 50 grit on a da sander but you will only be able to get to the nickel plating. Link to info/product at rockler], i believe the paint would stick good enough to satisfy most people.
Spray the brass or gold fixture with a light coat of primer. If they're not chromed, of course, you can skip the step to strip them. It will become progressively worse if it is not removed and the surface refinished.
Then, wipe down the chrome surface with wax and grease remover so it's clean when you paint it. Powder coatings have been applied successfully over chrome plating for many years. This special primer will grip to the metal and prepare you for regular primer and paint.
I recommend that you first neutralize the surface and remove any salts from the plating system by first rinsing the parts in virgin di water. Next i set the parts up on a stand in the spray booth. Of course, don't forget to dry the parts before powder coating.
Not perfect but will last for a long while. Last, but most definitely not least, it is time to spray on your chrome paint. I stripped the chrome from the chromed sprues in the old monogram red baron hot rod, by the way, because i wanted to be able to clean up seams and sprue gates on chromed parts (eg, the fuel.
Once the primer is dry, apply automotive paint to the. Rust can cause unsightly and expensive damage to a smooth, shiny surface such as a chrome bumper or boat rigging. Sand the chrome so that the gloss is completely gone.
Your biggest problem when painting over chrome will be adhesion. Instead of using sand paper, you'll need to get a finishing pad to rough up the surface of the chromed metal you are wanting to paint over. Your question about candy color makes me think that.
Lastly make sure you’re painting over actual chrome plating. A pit in the chrome left alone will pop out in no time and ruin your paint. To paint over a chrome surface, start by sanding it so the paint is able to stick to it.
Once there, prep work is the key. Applying paint directly over smooth, shiny chrome is asking for adhesion issues. Also, antique chrome has a look of a fine pattern of holes, hazes, and for lack of a better term, cloudiness.
And clean again with a dry rag. Continue to spray the primer onto the fixture until you have lightly covered over the brass or gold. You must get below any damaged spots.
Keep the spray can at least 4 to 6 inches from the surface of the fixture to avoid overspray and running primer. (no shine on the chrome at all.) then clean with wax & grease remover on a rag. Wait four hours for the metal to dry.
Prep** using 240g dry sandpaper, by hand or on an air or electric disc sander. Use an etching primer and then paint. Be sure you have good lighting for this, since the clear will not show a color to follow but only a shine on the sprayed areas.
Spray on the chrome paint. My experience with this is the chrome actually never comes off. I would strip them as was discussed above, and then paint them with a gold metallic.
Two light to medium coats will do.

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